Frontend versus launcher
EmulationStation, and EmulationStation Desktop Edition, is a frontend. It reads a gamelist, shows the artwork, and boots the emulator you configured in an XML or a menu. It is the screen on a lot of retro handhelds and living-room PCs. It is free and open source.
RetroApp does the scan, the metadata, and the session in one place. There is no gamelist.xml to repair when a path changes. The cost of that convenience is that you are not picking every emulator flag yourself on day one.
Who should stay on EmulationStation
If the machine is a dedicated box, a Steam Deck setup you already love, or a handheld image that boots straight into ES, there is no reason to rip it out. The theme library is larger, and the interface is built for a controller from the first pixel.
Windows is where ES is the weaker daily driver. ES-DE runs there, but the happy path is still 'install emulators, write the config, scrape.' RetroApp's happy path on Windows, macOS, and Linux is the library folder.
What RetroApp adds on top of a frontend
A frontend does not know that your friend is free tonight. ES will not sync a save to another PC or open a party code. Those are the reasons to add RetroApp even if ES stays on the TV box: the living room keeps its theme, the library you actually grow lives where the sessions are.
You can import an ES gamelist so the names you already cleaned up are not retyped. Covers can be rescraped. BIOS files still follow the same rules as anywhere else: PS1 and PS2 need a dump from your console, SNES does not.
For a single-player Saturday, ES and RetroApp can both launch the same ROM. The difference shows up when you want rewind without a hotkey worksheet, or a friend in the same game without a separate netplay tutorial. Read the LaunchBox comparison if the alternative you are leaving is Big Box rather than ES.
Download RetroApp · BIOS guide · Save states · Best retro launcher · vs LaunchBox · vs Playnite · vs EmulationStation
RetroApp vs EmulationStation is a launcher comparison. Specialized emulators stay better at their one console. The table above is the feature split. The text is the part that should decide the install.